A NOVEL METHOD FOR BIRCH OUTER BARK QUALITY CONTROL USING HIGHER HEATING VALUE

Janis Rizhikovs, Aigars Paze, Ance Plavniece, Kristaps Stankus, Inguss Virsis


Last modified: 09.05.2017

Abstract

In plywood plants, the bark of a birch tree is a readily accessible and already concentrated feedstock for further processing. It consists of two distinct layers: outer bark and inner bark. Up to 25.7 % of biologically active compounds (betulin, lupeol, betulinic acid) are concentrated in outer bark, with a broad spectrum of applications in the chemical, pharmaceutical, cosmetic and food industries. The inner bark must be separated from outer bark as well as possible because it causes a decrease in the yield and purity of the prepared ethanol extractives. Therefore, it is very important to predict the content of inner bark in the feedstock taken for the extraction process.

A novel method for the characterization of feedstock was developed using the higher heating value (HHV) as a reference. The developed method for birch outer bark quality control is very useful in birch outer bark extraction plants. Thus, it would be possible to control the purity of the feedstock and to predict the potential yield of extractives as well as the amount of the solvent to be taken for the extraction process. Pure enough (≥90 % of outer bark) feedstock for biologically active extractives production can be obtained by the floating method after 5 h if the HHV is more than 32-33 MJ/kg.

 


Keywords


Birch bark; feedstock quality; polysaccharides; higher heating value

References


[1]     E. Bergelin and B. Holmbom, "Reactions and distribution of birch extractives in kraft pulp oxygen delignification," J. Wood Chem. Technol., vol. 28, pp. 261-269, 2008.

[2]     P. C. R. O. Pinto, A. F. Sousa, A. J. D. Silvestre, C. P. Neto, A. Gandini, Ch. Eckerman and B. Holmbom, "Quercus suber and Betula pendula outer barks as renewable sources of oleochemicals: A comparative study," Ind. Crops Prod., vol. 29, pp. 126-132, 2009.

[3]     J. Rizhikovs, J. Zandersons, G. Dobele and A. Paze, "Isolation of triterpene-rich extracts from outer birch bark by hot water and alkaline pre-treatment or the appropriate choice of solvents," Ind. Crops Prod., vol. 76, pp. 209-214, 2015.

[4]     S. Alakurtti, T. Mäkelä, S. Koskimies and J. Yli-Kauhaluoma, "Pharmacological properties of the ubiquitous natural product betulin," Eur. J. Pharm. Sci., vol. 29, pp. 1-13, 2006.

[5]     A. Gandini, C. P Neto and A. J. D. Silvestre, "Suberin: a promising renewable resource for novel macromolecular materials," Prog. Polym. Sci., vol. 31, pp. 878-892, 2006.

[6]     J. Rizikovs, J. Zandersons, A. Paze, A. Tardenaka and B. Spince, "Isolation of suberinic acids from extracted outer birch bark depending on the application purposes," Baltic Forestry, vol. 20, pp. 98-105, 2014.

[7]     A. J. Mian and T. E. Timell, "Isolation and characterization of a cellulose from the inner bark of white birch (Betula Papyrifera)," Can. J. Chem., vol. 38, pp. 1191-1198, 1960.

[8]     D. N. Vedernikov, N. Yu. Shabanova and V. I. Roshchin, "Change in the chemical composition of the crust and inner bark of the Betula pendula Roth. birch (Betulaceae) with tree height," Russ. J. Bioorganic Chem., vol. 37, pp. 877-882, 2011.

[9]     A. Karnaouri, U. Rova and P. Christakopoulos, "Effect of different pretreatment methods on birch outer bark: New biorefinery routes," Molecules, vol. 21, pp. 427-443, 2016.

[10]  A. V. Obolenskaya, Z. P. Elnitsdkaya and A. A. Leonovich, Laboratory Works in the Chemistry of Wood and Cellulose (source is in Russian). Moscow: Ecologya, 1991.

[11]  A. Bredihhin, U. Mäeorg and L. Vares, "Evaluation of carbohydrates and lignocellulosic biomass from different wood species as raw material for the synthesis of 5-bromomethyfurfural," Carbohydr. Res., vol. 375, pp. 63-67, 2013.